It has long been known that fragrances or scents in products used indoors (e.g., in cleaning products, air fresheners, personal care products) are a source of indoor air pollution due to the chemicals in the fragrances. But it turns out that there is another reason to avoid scented cleaning products - they produce nanoparticles that are inhaled deep into the lungs.
A small study found that fragrances in scented cleaning products (both conventional and essential oil or botanical cleaning products) emit small ultrafine particles called nanoparticles that travel deep into a person's lungs within minutes. This is because chemicals in the scented cleaning products quickly react with ozone indoors. The inhaled particle dose can sometimes be equivalent to or greater than standing near heavy traffic! This is invisible air pollution - we can not see the nanoparticles, but they get deep into the lungs.
Bottom line: Choose unscented cleaning products. Also, use exhaust fans when cleaning, and open windows for a short while to improve ventilation.
From Science Daily: That fresh cleaning smell could be filling your home with nanoparticles
A room that smells like citrus, pine, or flowers is often associated with cleanliness. Those familiar scents, however, can signal chemical reactions taking place in the air.
Research led by Brandon Boor at Purdue University found that fragrance compounds released by both conventional cleaners and botanical essential oil-based products can rapidly react indoors and generate nanoparticles. If inhaled, some of these extremely small particles can penetrate deep into the lungs.
The researchers say exposure can be reduced by choosing unscented products, improving ventilation with exhaust fans or open windows, and avoiding devices that generate ozone while scented cleaning products are being used.
The researchers presented their results at the fall meeting of the American Chemical Society (ACS) during the "Healthy Indoor Spaces: Bridging the Microbiome and Chemistry" symposium in McCormick Place.
"We showed that indoor ozone reactions with fragrances from cleaning produce nanoparticles that carry a respiratory dose comparable to, or greater than, what you would experience from standing outside along a busy road," says Boor, an Assistant Professor of Civil and Construction Engineering at Purdue University who studies indoor air quality. "The particles are different in terms of their composition, but the total dose can be higher. You're not seeing smoke, dust, or haze in the air. Instead, you think the air smells great so it must be clean."
Boor began investigating how cleaning agents and chemical disinfectants affect indoor environments during the COVID-19 pandemic with his colleague Nusrat Jung, a Purdue Assistant Professor of Civil and Construction Engineering. One feature quickly stood out: many of the products people use to clean and disinfect indoor spaces contain strong fragrances.
"That's often to create a pleasant smellscape in the indoor space," says Boor. "But clean air should not smell like highly concentrated citrus fruit. It should not really smell of anything."
Scientists who study the atmosphere have long known that compounds released by plants can react with ozone. Terpenes such as pinene from pine trees, for example, can participate in reactions that generate tiny airborne particles. Over time, those particles can combine and grow until they become large enough to help seed clouds.
That chemistry proceeds relatively slowly in forests because the amount of terpenes in outdoor air is generally low. Indoors, the situation can be very different. Scented cleaners release terpenes when fragrance compounds evaporate from sprayed droplets or cleaned surfaces.
Cleaning liquids commonly contain compounds including pinene, limonene (lemon), thymol (thyme), and linalool (lavender). Their concentrations during cleaning can be far higher than levels typically measured outdoors. Boor says airborne terpene concentrations inside a room during cleaning can rise to tens or even hundreds of times those found in a forest.
To examine what happens under realistic conditions, the researchers tested scented conventional liquid products as well as botanical-containing disinfectant sprays and wipes inside a model home on Purdue's campus.
Routine tasks such as mopping floors, spraying countertops, and wiping surfaces with scented products generate billions or trillions of particles, with the total depending on the product.
Most were nanoparticles or ultrafine particles measuring only 1-30 nanometers across. Because particles this small often fall outside the detection range of at-home air quality monitors, people may have no indication that particle concentrations have risen.
The researchers found that ordinary cleaning can temporarily push ultrafine particle levels above those measured outdoors.
Their tiny size is important from a health perspective. Ultrafine particles can settle throughout the respiratory tract and reach deep regions of the lungs. Once there, they can contribute to irritation and inflammation in the respiratory system. Some may also have the potential to enter the bloodstream.
One of the biggest surprises was the speed of the process. Particle formation and growth occurred within just minutes. "By the time you finish cleaning up an indoor space, you've already formed a lot of nanoparticles and inhaled them," says Boor.
Ozone Can Intensify Indoor Particle Formation
More recently, Boor and Ernest Blatchley, a Professor at Purdue, studied what happens when scented surface cleaners are used at the same time as germicidal far-UV (UV-C) lamps designed to disinfect indoor air.
The combination created particularly favorable conditions for nanoparticle formation.
The lamps interact with oxygen in the air and produce ozone. During experiments in the tiny home, ozone concentrations increased to roughly 20 to 40 parts per billion. Those levels were comparable to, although somewhat below, the outdoor ozone concentrations measured when the experiments were performed.
With both elevated ozone and high concentrations of terpenes present, nanoparticle production became even more intense. That combination raised additional concerns about the amount of particulate matter occupants could inhale.
How to Reduce Exposure While Cleaning
Boor emphasizes that the goal is to help consumers make informed choices rather than discourage cleaning. Cleaning remains important for removing viruses and bacteria from surfaces, but several simple measures may reduce exposure to the secondary pollution produced during the process.
The researchers recommend:
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- Choose low-fragrance or fragrance-free products.
- Avoid applying several scented products in the same cleaning session.
- Run exhaust fans or open windows to ventilate the space.
- Do not simultaneously clean surfaces with scented products while using ozone-generating devices, such as far UV-C lamps.